Dielectric Constant

The dielectric constant (ε, Greek epsilon) is a property of a solvent. It is a measure of how well the solvent reduces interactions between ions in solution. A dielectric constant greater than or equal to 20 means the medium is a good solvent (ie, at 20°C dH2O has an ε ≈ 80) and an ε below that means the medium is a poor solvent (ie,at 20°C acetic acid has an ε ≈ 6).

F = [ k · q1 · q2 ] / [ ε · r2 ]

F Given two charges (ie, Na+ and Cl-, they exert a force F on each other, either attractive or repulsive.
k Proportionality constant.
q1
q2
Magnitude of the charges.
r Distance between the charges.
ε Dielectric constant of the surrounding medium.

Written by      First published April 20, 2011      Last modified July 28, 2011
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